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Titre :	Interfacial forces in aqueous media Ajouter au panier
Auteur(s) :	Carel J. Van Oss
Type de document :	Livre
Sujets :	TECHNIQUE ANALYTIQUE ; POLYMERE ; SOLUBILITE ; ADSORPTION ; TENSION SUPERFICIELLE ; ADHESIVITE
Résumé :	Thoroughly revised and reorganized, the second edition of Interfacial Forces in Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van der Waals and electrical double layer interactions, as well as Lewis acid–base interactions between colloidal entities in polar liquids such as water. New in this Edition: Four previously unpublished chapters comprising a new section on interfacial properties and structure of liquid water New material throughout the text on the interplay between macroscopic-scale repulsions and microscopic-scale attractions in protein adsorption A new chapter covering i[...] Thoroughly revised and reorganized, the second edition of Interfacial Forces in Aqueous Media examines the role of polar interfacial and noncovalent interactions among biological and nonbiological macromolecules as well as biopolymers, particles, surfaces, cells, and both polar and apolar polymers. The book encompasses Lifshitz-van der Waals and electrical double layer interactions, as well as Lewis acid–base interactions between colloidal entities in polar liquids such as water. New in this Edition: Four previously unpublished chapters comprising a new section on interfacial properties and structure of liquid water New material throughout the text on the interplay between macroscopic-scale repulsions and microscopic-scale attractions in protein adsorption A new chapter covering interfacial tension determination A new chapter examining the kinetics and energetics of protein adsorption onto metal oxide surfaces Dr. van Oss describes the nature of the various manifestations of hydrophobic interactions as well as of hydration pressure and analyzes the measurement of the contact angles that result when liquid droplets are deposited on flat solids. He also covers coacervation and complex coacervation, discusses the determination methods of electrokinetic potentials, and treats some of the lesser-known properties of water, such as cluster formation and the hydrophobicity of the water-air interface. Principally involved in multiple applications of colloids and interface science for more than 50 years, Carel Jan van Oss is Editor Emeritus of Immunological Investigations and Founding Editor of Preparative Biochemistry and Biotechnology and of Separation and Purification Reviews. He is an editorial advisor for the Journal of Dispersion Science and Technology. In addition to these Taylor & Francis journals, Dr. van Oss is the author, coauthor, or editor of eleven books, including Colloid & Surface Properties of Clays and Related Minerals (2002), and over 350 scientific papers and chapters.
Editeur(s) :	Boca Raton : CRC Press
Date de publication :	2006
Mention d'édition :	2nd ed.
Format :	1 vol. (438 p.) / ill. / 25 cm
Note(s) :	Bibliographie Illustrations Index
Table des matières :	Chapter I Introduction Non-Covalent Interactions van der Waals Forces Polar, or Lewis Acid-Base (AB) Interactions Electrostatic (EL) Interactions Other Non-Covalent Forces Brownian Movement (BR) Forces General Bibliography PART I Theory Chapter II Lifshitz–van der Waals (LW) Interactions van der Waals Forces Macroscopic Approximation The Lifshitz Approach Interfacial Lifshitz–van der Waals Interac[...] Chapter I Introduction Non-Covalent Interactions van der Waals Forces Polar, or Lewis Acid-Base (AB) Interactions Electrostatic (EL) Interactions Other Non-Covalent Forces Brownian Movement (BR) Forces General Bibliography PART I Theory Chapter II Lifshitz–van der Waals (LW) Interactions van der Waals Forces Macroscopic Approximation The Lifshitz Approach Interfacial Lifshitz–van der Waals Interactions Additivity of the Three Electrodynamic Contributions to the Surface Tension Coda Chapter III Relation Between the Hamaker Constant and the Apolar Surface Tension Component Proportionality Factor A/γLW Signifi cance of the Averaged Value Applicability of Eq. [III-1] to A12, A121, A132 Coda Chapter IV Polar or Lewis Acid-Base Interactions Interfacial Lewis Acid-Base Interactions The Young-Dupré Equation Attractive and Repulsive Polar Forces Relative Values of the Electron-Acceptor and Electron-Donor Parameters of γ Monopolar Surfaces and Substance Different Modes of Interaction Between Two Polar Substances The Surface Tension of Liquids and Solids Interfacial Tensions Between Polar Liquids Earlier Approaches to Correlate Contact Angles and Surface Tensions in Polar Systems Comparison Between Repulsive Lifshitz–van der Waals and RepulsiveAcid-Base Interactions The Mechanisms Allowing ΔGLW132 and ΔGAB131 to Be Positive Implications of ΔGAB132 > 0 Implications of ΔG132 > 0 Connection Between “Hydrophobic” and Hydrophilic Interactions Coda Chapter V Electrical Double Layer Interactions Electrokinetic Potential and Ionic Double Layer Free Energy of Electrostatic Interactions Electrokinetic Phenomena ζ-Potential, Ionic Strength and Electrokinetic Mobility Influence of the Double Layer Thick Double Layer Thin Double Layer Relaxation Validity Ranges of the Equations Confrontation of the Equations with Experimental Data Small κa Large κa Transition 0.1 < κa < 300 Calculation of ζ-Potentials from Mobility Data The Brooks Effect Coda Chapter VI Brownian Movement Forces—Osmotic Interactions of Polymers Brownian Movement Forces Osmotic Interactions Radius of Gyration Polymer Concentration Size and Shape of Polymer Molecules Coda Chapter VII Rate of Decay with Distance Unretarded Lifshitz–van der Waals Forces Retarded London–van der Waals Forces Polar (AB) Interactions Electrical Double Layer Interactions Brownian Movement Interactions Combined Interaction Forces Acting on Solids or on Suspended Particles in Polymer Solutions The Derjaguin Approximation Energy-Balance Diagrams Coda PART II Interfacial Properties and Structure of Liquid Water Chapter VIII Lifshitz–van der Waals and Lewis Acid-Base Properties of Liquid Water—Physical and Physico-Chemical Effects Dominance of the Lewis Acid-Base Properties of Water Effect of Temperature on the γ-Components of Water The Surface Properties of Ice at 0°C Cluster Formation in Liquid Water Coda Chapter IX Role of Water in Hydrophobic Attraction The Hydrogen-Bonding (Lewis Acid-Base) Free Energy of Cohesion of Water and “the Hydrophobic Effect” Hydrophobic Hydration Clathrate Formation Action at a Distance Modulation of the Hydrophobizing Capacity of Water Decreasing \| ΔGABiwi \| Increasing \| ΔGABiwi \| Coda Chapter X Role of Water in Hydrophilic Repulsion Water and Hydration Forces Negative γiw Values and Hydrophilic Repulsion Hydration Orientation and Action at a Distance Hydrophilicity and Hydration Orientation Hydration Orientation of Proteins Modulation of the Hydrophilic Repulsion Through Temperature Changes Raising ΔGABiwi Lowering ΔGABiwi Coda Chapter XI The Water–Air Interface Hyper-Hydrophobicity of Air at the Water–Air Interface Quantitative Expression of the Total Hydrophobic Attraction Energy at the Water–Air Interface Absence of Hydration of Air at the Water–Air Interface Attraction of Partly Polar, or Amphiphilic Solutes to the Water–Air Interface, Which decreases the Apparent Surface Tension of Water Repulsion of Hydrophilic, or Near-Hydrophilic Solutes by the Air-Side of the Water–Air Interface; the Increase of the Surface Tension of Aqueous Solutions by the Admixture of Sugars and Salts The ζ–Potential of Air Bubbles in Water Coda PART III Experimental Measurement Methods Chapter XII Contact Angle and Surface Tension Determination and Preparation of Solid Surfaces The Sessile Drop as a Force Balance Spreading Pressure Contact Angle Measurement in Air–Hysteresis Contact Angles on Heterogeneous Surfaces—Cassie’s Equation Contact Angle Measurement in Liquids Contact Angle Measurement by Wicking Surface Tension of Liquids Apolar and Polar Surface Tension Component of Liquids Estimation of the Polar Surface Tension Parameters γL⊕ and γL⊖ of Liquids Gel Method Polar Solids Method Purity of Contact Angle Liquids Surface Tension and Surface Free Energy Influence of Temperature on the Properties of Water as a Contact Angle Liquid Influence of the pH of Water as a Contact Angle Liquid on the Surface Properties of Electrically Charged Solid Surfaces Infl uence of the pH of Water on the Properties of Water Itself, in Connectionwith Its Use as a Contact Angle Liquid Preparation of Solid Surfaces Particles and Cells Dried Solutes Hydrated Solutes Coda Chapter XIII Interfacial Tension Determination—Influence of Macroscopic- and Microscopic-Scale Interactions Interfacial Tensions and Free Energies of Interfacial Interaction Interfacial Tension Between Immiscible Liquids Determination of Interfacial Tensions Between Condensed-Phase Materials and Water The Aqueous Solubility Approach for Determining γowo Use of the cmc of Surfactant Molecules for Determining their γowo Contact Angle-Based Methods for Determining γowo Chapter XIV Different Approaches for Interpreting Contact Angles and Determining the Surface Tension and Surface Tension Components of Solids The Concept of Surface Tension of a Solid Critical Surface Tensions of Solids “Equation of State” Approaches The Concept of a Single Polar Surface Tension Component, “γP”,in Conjunction with a Geometric Mean Combining Rule Comparison Between the γ12AB and the“γ12P” Approaches Sedimentation of Particle Suspensions Advancing Solidification Fronts Adhesion Methods Other Approaches γLW and Hamaker Constants Phase Separation Electrophoretic Mobility Coda Chapter XV Electrokinetic Methods Microelectrophoresis of Particles and Cells Moving Boundary Electrophoresis Zone Electrophoresis Zone Electrophoresis of Particles and Cells Descending Density Gradient Electrophoresis Ascending Electrophoresis Packed Column Cell Electrophoresis Enhanced Electrophoretic Separation of Subclasses of Cells Through Receptor-Tagging Microgravity Electrophoresis Molecular Sieve Zone Electrophoresis Starch Gel Electrophoresis Polyacrylamide Gel Electrophoresis Sodium Dodecyl Sulfate Polyacrylamide Electrophoresis Graded Porosity Gel Electrophoresis Gel Electrophoresis of Nucleic Acid Zone Electrophoresis of Adsorbed Proteins Continuous Flow Electrophoresis Curtain Electrophoresis Free Flow Electrophoresis Endless Belt Electrophoresis Cylindrical Rotating Continuous Flow Electrophoresis Stable Flow Electrophoresis Electrophoretic Field Flow Fractionation Horizontal Rotating Cylinder Electrophoresis Capillary Electrophoresis Isoelectric Focusing Cell Isoelectric Focusing Isotachophoresis Bidimensional Methods Electroosmosis Streaming Potential and Sedimentation Potential Electrophoresis in Non-Aqueous Media Coda and Limitations Chapter XVI Direct Measurement Methods, Treating the Force Balance in Particular Force Balance Other Approaches Interfacial Attraction Effects (Hydrophobic Interactions) in Water Interfacial Repulsion Effects (Hydration Repulsion) in Water Interactions Between Adsorbed Polymer Layers in Apolar Media Interaction Between Adsorbed Biopolymers and Between Adsorbed Phospholipids in Aqueous Media Measurement of the Decay-Length of Water Electrostatic Effects Oscillatory Effects Atomic Force Microscopy Coda PART IV Associated Phenomena and Applications Chapter XVII Surface Tension Components and Parameters of Liquids and Solids Completely Apolar Liquids Monopolar Liquids, Immiscible with Water Dipolar Liquids, Immiscible with Water Naphthalene Monopolar and Dipolar Water-Miscible Liquids Synthetic Polymers Biopolymers Plasma Proteins Other Proteins Carbohydrates Nucleic Acids Contact Angle Liquids Surface Tension Properties of Clays and Other Minerals Coda Chapter XVIII Attractive LW- and AB-Forces: Hydrophobic Interactions Interaction Between Two Identical Organic Molecules, Immersed in Water Enthalpy and Entropy of Hydrophobic Interactions Apolar (LW) and Polar (AB) Contributions to Hydrophobic Interactions Hydrophobic Attractions (ΔGiwi) Hydrophobic Hydration (ΔGiw) Conclusions Propagation at a Distance of Attractive Hydrophobic Interactions Cavitation Is an Effect, Not a Cause of Hydrophobic Interactions;When Wiwi Is Smaller than Wiwi, Cavitation Is Favored Near the Interface Attractive Interfacial Interactions in Non-Aqueous Media Further to the Mechanism of Hydrophobic Interactions Occurrence of Attractive Interfacial (“Hydrophobic”) Interactions Between Similar Sites Interactions Between Two Different Organic Compounds Immersed in Water Occurrence of Attractive Interfacial (“Hydrophobic”) Interactions Between Two Dissimilar Sites Coda Chapter XIX Repulsive AB-Forces: Hydrophilic Interactions—Osmotic Pressures of PEO Solutions Negative Interfacial Tensions and Polar Repulsion Monopolar Surfaces Quantitative Expression of Hydrophilicity and Hydrophobicity Propagation at a Distance of Repulsive Hydrophilic Interactions Linkage Between EL and AB Forces Osmotic Pressure Effects Osmotic Pressures of PEO-Water Solutions Monopolar Repulsion Between Dissimilar Polar Entities Monopolar Repulsion in Non-Aqueous Polar Media Persistence of ΔGiwi Interactions at a Distance Coda Appendix: On the Interpolation of Values of γ12 versus PEO Concentration Chapter XX The Primary and Secondary Interactions van der Waals Interactions (Primary) Electrostatic, or Coulombic Interactions (Primary) Lewis Acid-Base Interactions (Primary) Brownian Movement Interactions Primary Forces and Secondary Phenomena Osmotic Pressure Disjoining Pressure Structural Forces Steric Interactions Depletion Interactions Entropy-Driven and Enthalpy-Driven Interactions Cross-Binding Interactions Specific Interactions Coda Chapter XXI Phase Separation in Polymer Solutions; Coacervation and Complex Coacervation Phase Separation of Polymers in Organic Media Phase Separation of Polymers in Aqueous Media Phase Separation of Water-Soluble Polymers in Polar Organic Media Mechanism of Polymer Phase Separation in Apolar Systems Mechanism of Polymer Phase Separation in Polar and Especially in Aqueous Systems The Interfacial Tension Between Aqueous Phases Use of Aqueous Two-Phase Systems for Cell and Biopolymer Separation Polymer Phase Separation Summarized Coacervation and Complex Coacervation Role of Low Molecular Weight Solutes in Coacervation Complex Coacervation Flocculation Phase Formation in Microemulsions Coda Chapter XXII Solubility of Polymers and Other Solutes Apolar Systems and Hildebrand’s Solubility Parameter Polar Systems Solubility of Apolar Polymers Miscibility of Polar Liquids Miscibility and Solubility as Microscopic-Scale Phenomena Miscibility and Immiscibility as Macroscopic-Scale Phenomena Conclusion Solubility of Polar Polymers Solubility in Non-Aqueous Polar Liquids Insolubilization of Biopolymers The Flory-Huggins χ-Parameter and the Solubility of Polar Compounds Solubility and the cmc of Non-Ionic Surfactants Relation Between ΔGTOT and the cmc Solubility and the cmc of Anionic Surfactants Solubility of Organic Liquids in Water Solubility of Electrolytes Coda Chapter XXIII Cell and Particle Stability Energy vs. Distance Plots in Aqueous Media Particle Stability vs. Flocculation—The Schulze-Hardy Mechanism of Flocculation with Plurivalent Counterions Polymer Molecules, Very Small Particles and Protuberances with Small Radii of Curvature The Glycocalyx of Mammalian Cells Blood Cell Stability Rouleau Formation of Red Cells, or Pseudo-Attachment at the Secondary Minimum Hemagglutination The IgG Molecule as a Probe for Determining the Intercellular Distance,l ,at the Secondary Minimum; Estimation of the Decay Length of Water Cell and Particle Stability in the Absence and in the Presence of Polymers Stability in the Absence of Polymers Stability Induced by Attached Lyophilic Polymers; Depletion Phenomena Coda Chapter XXIV Adsorption and Adhesion in Aqueous Media, Including Ligand-Receptor Interactions Interaction Between Two Different Materials Immersed in Water Macroscopic and Microscopic-Scale Interactions Adsorption Influence of the Size of the Solute Blotting Protein Adsorption Change in Configuration and Denaturation Liquid Chromatography Cell Adhesion Influence of Protein Adsorption Adhesion to High- and Low-Energy Surfaces Prevention of Adhesion The Influence of Cell-Shape on Adhesiveness Cell Adhesion to Low-Energy Surfaces Aspecific and Specific Interactions in Microbial Adhesion Microbial Pathogenicity and Negative and Positive Cell Adhesion Opsonization and Phagocytosis Cell Fusion Cell Freezing and Negative and Positive Adhesion to Advancing Ice Fronts Aspecific and Specific Interactions Smallness of Specific Sites Interfacial (LW + AB) Specific Interactions Role of Direct Hydrogen Bonding in Specific Interactions H-Bonds Used in Ag-Ab Modeling Role of H-Bonding in Specific Interactions in General Specific Electrostatic Interactions Bridging with Plurivalent Counterions—Calcium Bridging Antigen-Antibody Binding Hysteresis Role of Hydration The ΔG1w2→ΔG12 Transition Specific Recombination DNA-DNA Interactions Summary of the Mechanism of Specific Ligand-Receptor Interactions Coda Chapter XXV Kinetics and Energetics of Protein Adsorption onto Metal Oxide Surfaces Measurement of the Kinetic On-Rate Constant of Protein Adsorption onto Metal Oxide Surfaces—Experimental Constraints to Be Observed Mass Transport Steric Hindrance by Dissolved Protein Molecules Decrease in the Adsorption of Protein onto Metal Oxide Surfaces When Dissolved in Some Common Buffer Solutions Macroscopic-Scale Repulsion Between Albumin and Glass or Silica Microscopic-Scale Attraction Between Proteins and Discrete Cationic Sites Imbedded in Hydrophilic Metal Oxide Surfaces Extended DLVO (XDLVO) Analysis of Protein Adsorption as a Function of Distance and Geometric Shape Incorporation of both Macroscopic-Scale Repulsion and Microscopic-Scale Attraction Energies in the Analysis of Measured Kinetic Association Rate Constants, Using von Smoluchowski’s Formalism von Smoluchowski’s Formalism von Smoluchowski’s Equation von Smoluchowski’s f Factor Determination of Xmac and Xmic Determination and Significance of ka mic Influence of Hysteresis on the Determination of Ka and kd and Method for Obviating Its Effects Coda List of Symbols Used
Langue(s) :	Anglais
Identifiant :	978-1-57444-482-7
Lien vers la notice :	https://infodoc.agroparistech.fr/index.php?lvl=notice_display&id=208826

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